Publications 2013

  • Mechanochemical degradation of lignin and wood by solvent-free grinding in a reactive medium
    T. Kleine, J. Buendia, C. Bolm, Green Chem. 201315, 160–166.

  • N-Cyano Sulfoximines: COX Inhibition, anti-Cancer Activity, Cellular Toxicity, and Mutagenicity 
    S. J. Park, H. Baars, H. Buschmann, J. M. Baron, P. M. Amann, K. Czaja, H. Hollert, K. Bluhm, R. Redelstein, C. Bolm, ChemMedChem 20138, 217–220.

  • Mild Copper-Mediated Direct Oxidative Cross-Couplings of 1,3,4-Oxadiazoles with Polyfluoroarenes Using Dioxygen as Oxidant 
    L. H. Zou, J. Mottweiler, D. L. Priebbenow, J. Wang, J. A. Stubenrauch, C. Bolm, Chem. Eur. J. 201319, 3302–3305.
    Selected by P. Knochel and N. M. Barl for Synfacts 2013, 9, 537. 

  • Organocatalytic solvent-free hydrogen bonding-mediated asymmetric Michael additions under ball milling conditions
    M. Jörres, S. Mersmann, G. Raabe, C. Bolm, Green Chem. 201315, 612–616.

  • Copper-Catalyzed Oxidative Cross-Couplings of Sulfoximines and Alkynes
    L. Wang, H. Huang, D. L. Priebbenow, F.-F. Pan, C. Bolm, Angew. Chem. 2013125, 3562–3564; Angew. Chem. Int. Ed. 2013, 52, 3478–3480.
    Selected by P. Knochel and N. M. Barl for Synfacts 2013, 9, 651. 
  • Mechanistic Insights into Copper-Catalyzed Sonogashira-Hagihara-Type Cross-Coupling Reactions: Sub-Mol% Catalyst Loadings and Ligand Effects
    L.-H. Zou, A. J. Johansson, E. Zuidema, C. Bolm, Chem. Eur. J. 2013, 19, 8144–8251. 
  • Base-Catalyzed Synthesis of Substituted Indazoles under Mild, Transition Metal-Free Conditions
    I. Thomé, C. Besson, T. Kleine, C. Bolm, Angew. Chem. 2013125, 7657–7661; Angew. Chem. Int. Ed. 201352, 7509–7513.
  • The copper-catalysed oxidative N-acylation of sulfoximines
    L. Wang, D. L. Priebbenow, L.-H. Zou, C. Bolm, Adv. Synth. Catal. 2013, 355, 1490–1494. 
  • The Disubstitution of Acetals to Prepare δ,δ-Bis(aryl) β-Ketoesters
    D. L. Priebbenow, L.-H. Zou, P. Becker, C. Bolm, Eur. J. Org. Chem. 2013, 3965–3969.
  • The Rhodium-Catalyzed Synthesis of Pyrrolidine-Substituted (Trialkylsilyloxy)Acrylic Esters
    D. L. Priebbenow, C. Bolm, RSC Adv. 2013, 3, 10318–10322. 
  • Enantioselective Nitrene Transfer to Sulfides Catalyzed by a Chiral Iron Complex
    J. Wang, M. Frings, C. Bolm, Angew. Chem. 2013125, 8823–8827; Angew. Chem. Int. Ed. 201352, 8661–8665.
    Selected by H. Hayashi and Y. Shimoda for Synfacts 2013, 9, 1188.
  • Recent Advances in the Willgerodt-Kindler Reaction
    D. L. Priebbenow, C. Bolm, Chem. Soc. Rev. 2013,
    42, 7870–7880. 
  • Acylsilanes: Valuable Organosilicon Reagents in Organic Synthesis
    H.-J. Zhang, D. L. Priebbenow, C. Bolm, Chem. Soc. Rev. 201342, 8540–8571. 
  • Rhodium-Catalyzed Oxidative Annulation of Sulfoximines and Alkynes as an Approach to 1,2-Benzothiazines
    W. Dong, L. Wang, K. Parthasarathy, F. Pan, C. Bolm, Angew. Chem. 2013125, 11787–11790; Angew. Chem. Int. Ed. 201352, 11573–11576. 
  • Phenyliodine Diacetate-Mediated para-Functionalizations of Amido- and Amino-substituted [2.2]Paracyclophanes
    P. Schaal, H. Baars, G. Raabe, I. Atodiresei, C. Bolm, Adv. Synth. Catal. 2013355, 2506–2512. 
  • Copper-Catalyzed Synthesis of α-Thioaryl Carbonyl Compounds Through S–S and C–C Bonds Cleavage
    L-H. Zou, D. L. Priebbenow, L. Wang, J. Mottweiler, C. Bolm, Adv. Synth. Catal.
    2013355, 2558–2563. 
  • Copper-Catalyzed C–N Cross-Coupling of Sulfondiimines with Boronic Acids
    R. Bohmann, C. Bolm, Org. Lett. 2013, 15, 4277–4279. 
  • Rhodium-Catalyzed C3-Selective Alkenylation of Substituted Thiophene-2-Carboxylic Acids and Related Compounds
    T. Litsuka, P. Schaal, K. Hirano, T. Satoh, C. Bolm, M. Miura, J. Org. Chem. 201378, 7216–7222. 
  • One-Pot Zinc-Promoted Asymmetric Alkynylation/Brook-Type Rearrangement/Ene-Allene Cyclization: Highly Selective Formation of Three New Bonds and Two Stereocenters in Acyclic Systems

    P. Smirnov, J. Mathew, A. Nijs, E. Katan, M. Karni, C. Bolm, Y. Apeloig, I. Marek, Angew. Chem. 2013, 125, 13962–13966Angew. Chem. Int. Ed. 201352, 13717–13721.
    by H. Yamamoto and A. Izumiseki for Synfacts 201410, 269.

  • Sulfoxides-to-Sulfimine Conversions: Use of Modified Burgess-type Reagents
    C. M. M. Hendriks, P. Lamers, J. Engel, C. Bolm, Adv. Synth. Catal. 2013, 355, 3363–3368.
  • Exploring the Reactivity of N-Alkynylated Sulfximines: [2+2]-Cyloadditions
    R. Pirwerdjan, D. L. Priebbenow, P. Becker, P. Lamers, C. Bolm, Org. Lett. 2013, 15, 5397–5399.
  • Copper-Catalyzed Oxidative Decarboxylative Couplings of Sulfoximines and Aryl Propiolic Acids
    D. L. Priebbenow, P. Becker, C. Bolm, Org. Lett. 2013, 15, 6155–6157.
  • Metal-catalyzed C(sp2)N bond formation
    A. Correa, C. Bolm, in Topics in Organometallic Chemistry (Eds.: D. Ma, M. Taillefer), Springer Verlag, 2013, 46, 55–85.