Publications 2014

  • Acylsilanes in Rh(III)-catalyzed directed aromatic C-H alkenylations and siloxycarbene reactions with C-C double bonds
    P. Becker, D. L. Priebbenow, R. Pirwerdjan, C. Bolm, Angew. Chem. 2014, 126, 273–275; Angew. Chem. Int. Ed. 2014, 53, 269–271.
  • Iron-Catalyzed Imidative Kinetic Resolutions of Racemic Sulfoxides
    J. Wang, M. Frings, C. Bolm,  Chem. Eur. J. 2014, 20, 966–969.

  • Transition-Metal-Free Synthesis of Benzimidazoles Mediated by KOH/DMSO
    H. Baars, A. Beyer, S. V. Kohlhepp, C. Bolm,  Org. Lett. 2014, 16, 536–539.

  • Photochemical Intermolecular Silylacylations of Electron-Deficient Internal Alkynes
    P. Becker, D. L. Priebbenow, H.-J. Zhang, R. Pirwerdjan, C. Bolm, J. Org. Chem. 2014, 79, 814–817.

  • Catalytic, Asymmetric Synthesis of Phosphonic γ-(Hydroxyalkyl)butenolides with Contiguous Quaternary and Tertiary Stereogenic Centers
    M. Frings, I. Thomé, I. Schiffers, F.-F. Pan, C. Bolm, Chem. Eur. J. 2014, 20, 1691–1700.

  • Rhodium(III)-Catalyzed Selective ortho-Olefinations of N-Acyl and N-Aroyl Sulfoximines by CH Bond Activation
    K. Parthasarathy, C. Bolm, Chem. Eur. J. 2014, 16, 4896–4900.

  • Light-Induced Ruthenium-Catalyzed Nitrene Transfer Reactions: A Photochemical Approach towards N-Acyl Sulfimides and Sulfoximines
    V. Bizet, L. Buglioni, C. Bolm, Angew. Chem. 2014, 126, 5745–5748; Angew. Chem. Int. Ed. 2014, 53, 5639–5642.

  • C–H Activation of Methyl Arenes in the MnO2-Mediated Aroylation of N-Chlorosulfoximines
    D. L. Priebbenow, C. Bolm, Org. Lett. 2014, 16, 1650–1652.
    Selected by P. Knochel and N. M. Barl for Synfacts 2014, 10, 627.

  • N-Alkylations of NH-Sulfoximines and NH-Sulfondiimines with Alkyl Halides Mediated by KOH in DMSO
    C. M. M. Hendriks, R. A. Bohmann, M. Bohlem, C. Bolm, Adv. Synth. Catal. 2014, 356, 1847–1852.

  • Iron-Catalyzed Hetero Cross-Dehydrogenative Coupling Reactions of Sulfoximines with Diarylmethanes: A New Route to N-Alkylated Sulfoximines
    Y. Cheng, W. Dong, L. Wang, K. Parthasarathy, C. Bolm, Org. Lett. 2014, 16, 2000–2002.

  • Carsten Bolm: Author profile
    C. Bolm, Angew. Chem. 2014, 126, 6714–6715; Angew. Chem. Int. Ed. 2014, 53, 6596–6597.

  • Directed Additions of 2-Arylpyridines and Related Substrates to Cyclic Imines through Rhodium-Catalyzed CH Functionalization
    K. Parthasarathy, A. Rebolledo Azcargorta, C. Bolm, Org. Lett. 2014, 16, 2538–2541.

  • N-Arylations of Sulfoximines with 2-Arylpyridines by Copper-Mediated Dual NH/CH Activation
    L. Wang, D. L. Priebbenow, W. Dong, C. Bolm, Org. Lett. 2014, 16, 2661–2663.

  • A New Chiral Glycine Equivalent for the Asymmetric Synthesis of α-Amino Acids under Operationally Convenient Conditions
    M. Jörres, X. Chen, J. L. Aceña, C. Merkens, C. Bolm, H. Liu, V. A. Soloshonok, Adv. Synth. Catal. 2014, 356, 2203–2208.

  • Methionine and Buthionine Sulfoximine: Syntheses under Mild and Safe Imidation/Oxidation Conditions
    L. Buglioni, V. Bizet, C. Bolm, Adv. Synth. Catal. 2014, 356, 2209–2213.

  • Fluorinated Sulfoximines: Syntheses, Properties and Applications
    V. Bizet, R. Kowalczyk, C. Bolm, Chem. Soc. Rev. 2014, 43, 2426–2438.

  • From gene towards selective biomass valorization: Novel bacterial β-etherases with catalytic activity on lignin-like polymers
    P. Picart, C. Müller, J. Mottweiler, L. Wiermans, C. Bolm, P. Domínguez de María, A. Schallmey, ChemSusChem 2014, 7, 3164–3171.

  • Copper-Catalyzed N-Alkynylations of Sulfoximines with Bromoacetylenes
    X. Y. Chen, L. Wang, M. Frings, C. Bolm, Org. Lett. 2014, 16, 3796–3799.
  • Hydroarylations of Heterobicyclic Alkenes through Rhodium-Catalyzed Directed C-H Functionalizations of S-Aryl Sulfoximines
    W. Dong, K. Parthasarathy, Y. Cheng, F. Pan, C. Bolm, Chem. Eur. J. 
    2014, 20, 15732–15726.
  • Rhodium-Catalyzed Intramolecular Dehydrogenative Aryl–Aryl Coupling Using Air as Terminal Oxidant
    H. Baars, Y. Unoh, T. Okada, K. Hirano, T. Satoh, K. Tanaka, C. Bolm, M. Miura, Chem. Lett. 2014, 43, 1782–1784.
  • (R)-(−)-2-[(5-Oxido-5-phenyl-5λ4-isoquino[4,3-c][2,1]benzothiazin-12-yl)amino]benzonitrile
    M. Frings, I. Atodiresei, C. Bolm, Molbank 2014, M834.
  • Formation of Three New Bonds and Two Stereocenters in Acyclic Systems by Zinc-Mediated Asymmetric Alkynylation of Acylsilanes, Brook Rearrangement and Ene-Allene Carbo­cyclization Reactions
    P. Smirnov, E. Katan, J. Mathew, A. Nijs, M. Karni, C. Bolm, Y. Apeloig, I. Marek, J. Org. Chem. 
    2014, 79, 12122–12135.