Publications 2016

  • Copper-Catalyzed Oxidative α-Ketoacylations of Sulfoximines with Aryl Methyl Ketones and Dioxygen as Terminal Oxidant
    H. Cheng, C. Bolm, Synlett 201627, 769–772.
  • Copper-Catalyzed Direct Sulfoximination of Heteroaromatic N-Oxides by Dual C–H/N–H Dehydrogenative Cross-Coupling
    H. Yu, Z. Li, C. A. Dannenberg, C. Bolm, Chem. Asian J. 2016, 11, 54–57.
  • Mechanochemical Iridium(III)-Catalyzed C-H Bond Amidations of Benzamides with Sulfonyl Azides under Solvent-Free Conditions in a Ball Mill
    G. N. Hermann, P. Becker, C. Bolm, Angew. Chem. 2016, 128, 3845–3848; Angew. Chem. Int. Ed. 2016, 55, 3781–3784.
    Selected as Very Important Paper.
  • Organocatalytic Kinetic Resolution of Sulfoximines
    S. Dong, M. Frings, H. Cheng, J. Wen, D. Zhang, G. Raabe, C. Bolm, J. Am. Chem. Soc. 2016, 138, 2166–2169.
    Selected by B. List and L. Liu for Synfacts 2016, 12, 634.
  • Copper-Catalyzed S–C/S–N Bond Interconversions
    J. Wen, H. Cheng, S. Dong, C. Bolm, Chem. Eur. J. 2016, 22, 5547–5550.
  • 1,2-Thiazines: One-Pot Syntheses Utilizing Mono- and Diaza-Analogs of Sulfones
    R. A. Bohmann, Y. Unoh, M. Miura, C. Bolm, Chem. Eur. J. 2016, 22, 6783–6786.
  • Mechanochemical enzymatic kinetic resolution of secondary alcohols under ball-milling conditions
    J. G. Hernández, M. Frings, C. Bolm, ChemCatChem 2016, 8, 1769–1772.
  • Mechanistic Insights into Iridium-Catalyzed Hydrogenations of α,β-Unsaturated Ketones
    J. Engels, S. Mersmann, P.-O. Norrby, C. Bolm, ChemCatChem 2016, 8, 3099–3106.
  • The Reactivity of Difluorocarbene with Hydroxylamines: Synthesis of Carbamoyl Fluorides
    H. Baars, J. Engel, L. Mertens, D. Meister, C. Bolm, Adv. Synth. Catal. 2016, 358, 22932299.
    Selected as Very Important Publication.
  • Halocyclizations of Unsaturated Sulfoximines
    H. Wang, M. Frings, C. Bolm, Org. Lett. 2016, 18, 2431–2434.
  • Rhodium-Catalyzed ortho-Amidations in the Preparation of Thiadiazine 1-Oxides
    Y. Cheng, W. Dong, H. Wang, C. Bolm, Chem. Eur. J. 2016, 22, 10821–10824.
  • Lithium Sulfondiimidoyl Carbanions
    R. A. Bohmann, J.-H. Schöbel, C. Bolm, Synlett 201627, 2201–2204.
  • Exploring the Reactivity of N-Alkynylated Sulfoximines: Acid-Catalyzed Cyclizations
    R. Pirwerdjan, P. Becker, C. Bolm, Org. Lett. 2016, 18, 3307–3309.
  • Synthesis of Sulfoximidoyl-Containing Hypervalent Iodine(III) Reagents and Their Use in Transition-Metal-Free Sulfoximidations of Alkynes
    H. Wang, Y. Cheng, P. Becker, G. Raabe, C. Bolm, Angew. Chem. 2016, 128, 12845–12848; Angew. Chem. Int. Ed. 2016, 55, 12655–12658.

    Selected by T. M. Swager and P. Wang for Synfacts 2016, 12, 1030.
  • Mechanochemical Strecker Reaction: Access to α-Aminonitriles and Tetrahydroisoquinolines under Ball Milling Conditions
    J. G. Hernández, M. Turberg, I. Schiffers, C. Bolm, Chem. Eur. J. 2016, 22, 14513–14517.
  • Building Block Approach for the Synthesis of Sulfoximines
    A.-D. Steinkamp, S. Wiezorek, F. Brosge, C. Bolm, Org. Lett. 2016, 18, 5348–5351.
    Selected by P. Knochel and J. M. Hammann for Synfacts 2016, 12, 1287.
  • Benzo[c]isothiazole-2-oxides: Three-Dimensional Heterocycles with Cross-Coupling und Functionalization Potential
    P. Lamers, L. Buglioni, S. Koschmieder, N. Chatain, C. Bolm, Adv. Synth. Catal. 2016, 358, 3649–3653.
  • Synthesis of a sulfonimidamide-based analog of Tasisulam and its biological evaluation in the melanoma cell lines SKMel23 and A375
    A.-D. Steinkamp, L. Schmitt, X. Chen, K. Fietkau, R. Heise, J. Baron, C. Bolm, Skin Pharmacol. Physiol. 2016, 29, 281–290.