Publications 2022

  • Selective Approaches to α- and β-Arylated Vinyl Ethers
    A. Domzalska-Pieczykolan, I. Funes-Ardoiz, B. Furman, C. Bolm, Angew. Chem. Int. Ed. 2022, 61, e202109801.
    Selected as Hot Paper.
  • Mechanochemical Grignard Reactions with Gaseous CO2 and Sodium Methyl Carbonate
    V. S. Pfennig, R. C. Villella, J. Nikodemus, C. Bolm, Angew. Chem. Int. Ed. 2022, 61, e202116514.
    Selected as Hot Paper. Also published as a preprint at ChemRxiv.
  • Mechanistic Insights on the Mechanosynthesis of Phenytoin, a WHO Essential Medicine
    F. Puccetti, S. Lukin, K. Užarević, E. Colacino, I. Halasz, C. Bolm, J. G. Hernández, Chem. Eur. J. 2022, 28, e202104409.
    Also published as a preprint at ChemRxiv.
  • Auger Emitter Conjugated PARP Inhibitor for Therapy in Triple Negative Breast Cancers: A Comparative In-Vitro Study
    R. Ambur Sankaranarayanan, J. Peil, A. T. J. Vogg, C. Bolm, S. Terhorst, A. Classen, M. Bauwens, J. Maurer, F. Mottaghy, A. Morgenroth, Cancers 2022, 14, 230.
  • PARP targeted Auger emitter therapy with [125I]PARPi-01 for triple-negative breast cancer
    R. Ambur Sankaranarayanan, A. Florea, S. Allekotte, A. T. J. Vogg, J. Maurer, L. Schäfer, C. Bolm, S. Terhorst, A. Classen, M. Bauwens, A. Morgenroth, F. M. Mottaghy, EJNMMI Res. 2022, 12, 60.
  • The Mechanochemical Synthesis and Activation of Carbon-Rich π-Conjugated Matarials
    M. Xuan, C. Schumacher, C. Bolm, R. Göstl, A. Herrmann, Adv. Sci. 2022, 9, 2105497.
  • Visible-Light-Mediated α-Ketoacylations of NH-Sulfoximines with gem-Difluoroalkenes
    Y. Tu, P. Shi, C. Bolm, Org. Lett. 2022, 24, 907–911.
  • Mechanochemical Palladium-Catalyzed Oxidative Esterification of Alcohols
    P. van Bonn, D. Dreßler, F. Weitenhagen, C. Bolm, ACS Sustainable Chem. Eng. 2022, 10, 1361–1366.
  • New Kids on the Block: Bile Salt Conjugates of Microbial Origin
    Ü. Ay, M. Leníček, A. Classen, S. W. M. Olde Damink, C. Bolm, F. G. Schaap, Metabolites 2022, 12, 176.
  • Visible Light-Promoted Synthesis of β-Keto Sulfoximines from N-Tosyl-Protected Sulfoximidoyl Chlorides
    P. Shi, Y. Tu, C. Wang, D. Ma, C. Bolm, J. Org. Chem. 2022, 87, 3817–3824.
  • Mechanochemical Solvent-Free N-Sulfenylations of Sulfoximines and Sulfonimidamides
    D. Kong, D. Ma, P. Wu, C. Bolm, ACS Sustainable Chem. Eng. 2022, 10, 2863–2867.
  • Introduction of Lipophilic Side Chains to NH-Sulfoximines by Palladium Catalysis Under Blue Light Irradiation
    D. Ma, D. Kong, P. Wu, Y. Tu, P. Shi, X. Wang, C. Bolm, Org. Lett. 2022, 24, 2238–2241.
  • Factors Governing the Catalytic Insertion of CO2 into Arenes – A DFT Case Study for Pd and Pt Phosphane Sulfonamido Complexes
    M. Hölscher, G. Kemper, S. Jenthra, C. Bolm, W. Leitner, Chem. Eur. J. 2022, 28, e202104375.
  • Stainless steel-initiated chloro sulfoximidations of allenes under solvent-free conditions in a ball mill
    D. Kong, M. M. Amer, C. Bolm, Green Chem. 2022, 24, 3125–3129.
  • 2-Formyl Benzamides from an N-Phthalimidoyl Sulfoximine
    Y. Tu, P. Shi, C. Bolm, Adv. Synth. Catal. 2022, 364, 1522–1525.
  • Mechanochemical Synthesis of Diarylethynes from Aryl Iodides and CaC2
    P. van Bonn, C. Bolm, Synlett 2022, 33, 893–897.
  • Sulfonimidamides by Sequential Mechanochemical Chlorinations and Aminations of Sulfinamides
    S. Terhorst, T. Jansen, T. Langletz, C. Bolm, Org. Lett. 2022, 24, 4109–4113.
  • Copper-Catalyzed, Aerobic Synthesis of NH-Sulfonimidamides from Primary Sulfinamides and Secondary Amines
    P. Wu, J. Demaerel, D. Kong, D. Ma, C. Bolm, Org. Lett. 2022, 24, 6988–6992.
  • Sulfondiimines: synthesis, derivatisation and application
    M. T. Passia, J.-H. Schöbel, C. Bolm, Chem. Soc. Rev. 2022, 51, 4890–4901.
  • Iron-catalyzed Intramolecular Arene C(sp2)–H Amidations under Mechanochemical Conditions
    P. Shi, Y. Tu, D. Kong, P. Wu, D. Ma, C. Bolm, Angew. Chem. Int. Ed. 2022, 61, e202204874.
    Selected as Hot Paper.
  • TACN-Mn Catalyst use in an Advanced Oxidation Process for Efficient Micropollutant Abatement in Wastewater: A Transformation Study of Diclofenac and Sulfamethoxazole
    J. Wolters, M. Usman, J. Mathiä, D. Dirichs, D. Bastian, B. Aumeier, C. Bolm, V. Linnemann, T. Wintgens, J. Environ. Chem. Eng. 2022, 10, 108320.
  • Stainless steel-initiated thiosulfonylations of unactivated alkenes under solvent-free conditions in a mixer mill
    D. Kong, C. Bolm, Green Chem. 2022, 24, 6476–6480.
  • The Preparation of Diaryl Sulfoxinium Triflates and Their Application in Palladium-Catalyzed Cross-Coupling Reactions
    C. Wang, X. Wang, D. Kong, K.-N. Truong, K. Rissanen, C. Bolm, Chem. Asian J. 2022, 17, e202200828.
  • Superbase-Mediated gem-Difluoroalkenylations of Sulfoximines
    X. Wang, C. Wang, C. Bolm, Org. Lett. 2022, 24, 7461–7464.
  • Evaluation of Chiral Organosulfur Compounds on Their Activity against the Malaria Parasite Plasmodium falciparum
    C. J. Ngwa, R. Stratmann, J. P. Musabyimana, K. Pannen, J.-H. Schöbel, M. Frings, I. Schiffers, C. Quaranta, S. Koschmieder, N. Chatain, G. Pradel, C. Bolm, Trop. Med. Infect. Dis. 2022, 7, 416.
  • Acid-Mediated Imidazole-to-Fluorine Exchange for the Synthesis of Sulfonyl and Sulfonimidoyl Fluorides
    M. T. Passia, J. Demaerel, M. M. Amer, A. Drichel, S. Zimmer, C. Bolm, Org. Lett. 2022, 24, 8802–8805.
  • Preparation of Enantiopure 3-Aminopiperidine and 3-Aminoazepane Derivatives from Ornithine and Lysine. Consecutive Syntheses of Pharmacologically Active Analogs, Such as Besifloxacin
    I. Schiffers, M. Frings, B. M. Kübber, K.-N. Truong, K. Rissanen, C. Bolm, Org. Process Res. Dev. 2022, 26, 2811–2822.
    Watch the video to see how (S)-3-(tritylamino)piperidin-2-one, an intermediate product from this publication, is purified by manual grinding.
  • Integration of adaptive syntheses in the sustainable production of biofuels and chiral fine chemicals
    M. Allhham, D. Rother, J.-D. Spöring, J. Wiesenthal, J. Klankermayer, V. Pfennig, C. Bolm, W. Graf von Westrap, A. Jupke, P. Siegert, Chem. Ing. Tech. 2022, 94, 1248–1249.