Cross Coupling Reactions

  • Copper-Catalyzed C(sp2)–S Coupling Reactions for the Synthesis of Aryl Dithiocarbamates with Thiuram Disulfide Reagents
    Z.-B. Dong, X. Liu, C. Bolm, Org. Lett. 2017, 19, 5916–5919.

  • Copper-Catalyzed Direct Sulfoximination of Heteroaromatic N-Oxides by Dual C–H/N–H Dehydrogenative Cross-Coupling
    H. Yu, Z. Li, C. A. Dannenberg, C. Bolm, Chem. Asian J. 2016, 11, 54–57.

  • Rhodium-catalyzed Intramolecular Dehydrogenative Aryl–Aryl Coupling Using Air as Terminal Oxidant
    H. Baars, Y. Unoh, T. Okada, K. Hirano, T. Satoh, K. Tanaka, C. Bolm, M. Miura, Chem. Lett. 2014, 43, 1782–1784.

  • Iron-Catalyzed Hetero Cross-Dehydrogenative Coupling Reactions of Sulfoximines with Diarylmethanes: A New Route to N-Alkylated Sulfoximines
    Y. Cheng, W. Dong, L. Wang, K. Parthasarathy, C. Bolm, Org. Lett. 2014, 16, 2000–2002.

  • Copper-Catalyzed C–N Cross-Coupling of Sulfondiimines with Boronic Acids
    R. Bohmann, C. Bolm, Org. Lett. 2013, 15, 4277–4279.

  • Rhodium-Catalyzed Oxidative Annulation of Sulfoximines and Alkynes as an Approach to 1,2-Benzothiazines
    W. Dong, L. Wang, K. Parthasarathy, F. Pan, C. Bolm, Angew. Chem. 2013, 125, 11787–11790; Angew. Chem. Int. Ed. 2013, 52, 11573–11576.

  • Mechanistic Insights into Copper-Catalyzed Sonogashira-Hagihara-Type Cross-Coupling Reactions: Sub-Mol% Catalyst Loadings and Ligand Effects
    L.-H. Zou, A. J. Johansson, E. Zuidema, C. Bolm, Chem. Eur. J. 2013, 19, 8144–8251.

  • Copper-Catalyzed Oxidative Cross-Couplings of Sulfoximines and Alkynes
    L. Wang, H. Huang, D. L. Priebbenow, F.-F. Pan, C. Bolm, Angew. Chem. 2013, 125, 3562–3564; Angew. Chem. Int. Ed. 2013, 52, 3478–3480. Selected by P. Knochel and N. M. Barl for Synfacts 2013, 9, 651.

  • Mild Copper-Mediated Direct Oxidative Cross-Couplings of 1,3,4- Oxadiazoles with Polyfluoroarenes Using Dioxygen as Oxidant
    L. H. Zou, J. Mottweiler, D. L. Priebbenow, J. Wang, J. A. Stubenrauch, C. Bolm, Chem. Eur. J. 2013, 19, 3302–3305. Selected by P. Knochel and N. M. Barl for Synfacts 2013, 9, 537.

  • Trace metal impurities in catalysis
    I. Thomé, A. Nijs, C. Bolm, Chem. Soc. Rev. 2012, 41, 979–987.

  • Transition Metal-Free Intramolecular N-Arylations
    I. Thomé, C. Bolm, Org. Lett. 2012, 14, 1892–1895.

  • Synthesis of N-Methyl-2-indolyl- and N-Methyl-2-benzo[b]furyl-Substituted Sulfoximines by Pd/Cu Co-catalyzed Domino Cross-Coupling/Cyclization Reactions
    R. F. Schumacher, A. Honraedt, C. Bolm, Eur. J. Org. Chem. 2012, 3737–3741.

  • Palladium-Catalyzed C–N Cross-Coupling of N'-Monosubstituted Sulfondiimines with Aryl Bromides
    M. Candy, R. Bohmann, C. Bolm, Adv. Synth. Catal. 2012, 354, 2928–2932.

  • Cross-Coupling Reactions (Editorial for the first Virtual Issue of the J. Org. Chem.)
    C. Bolm, J. Org. Chem. 2012, 77, 5221–5223, C. Bolm, Org. Lett. 2012, 14, 2925–2928.

  • Microwave-assisted solvent- and ligand-free copper-catalysed cross-couplings between halo pyridines and nitrogen nucleophiles
    Z.-J. Liu, J.-P. Vors, E. R. F. Gesing, C. Bolm, Green Chem. 2011, 13, 42–45.

  • Potassium Hydroxide/Dimethyl Sulfoxide-Promoted Intra-molecular Cyclization for the Synthesis of Benzimidazol-2-ones
    A. Beyer, C. M. M. Reucher, C. Bolm, Org. Lett. 2011, 13, 2876–2879.

  • Sub-Mol% Catalyst Loading and Ligand-Acceleration in the Copper-Catalyzed Coupling of Aryl Iodides and Terminal Alkyenes
    E. Zuidema, C. Bolm, Chem. Eur. J. 2010, 16, 4181–4185.

  • Kinetic Investigation of a Ligand-Accelerated Sub-mol% Copper-Catalyzed C–N Cross-Coupling Reaction
    P.-F. Larsson, C. Bolm, P.-O. Norrby, Chem. Eur. J. 2010, 16, 13613–13616.

  • DMSO/KOH: A Superbase for the Transition Metal-free Preparation of Cross-Coupling Products
    Y. Yuan, I. Thomé, S. H. Kim, D. Chen, A. Beyer, J. Bonnamour, E. Zuidema, S. Chang, C. Bolm, Adv. Synth. Catal. 2010, 352, 2892–2898.

  • Iron(III) chloride in Oxidative C–C coupling Reactions
    A. A. O. Sarhan, C. Bolm, Chem. Soc. Rev. 2009, 38, 2730–2744.

  • On the Role of Metal Contaminants in Catalyses with FeCl3
    S. L. Buchwald, C. Bolm, Angew. Chem. 2009, 121, 5694–5695; Angew. Chem. Int. Ed. 2009, 48, 5586–5587.

  • Copper-Catalyzed Cross-Couplings with Parts-per-Million Catalyst Loadings
    P.-F. Larsson, A. Correa, M. Carril, P.-O. Norrby, C. Bolm, Angew. Chem. 2009, 121, 5801–5803; Angew. Chem. Int. Ed. 2009, 48, 5691–5693.

  • Iron-Catalyzed C-O Cross-Coupling of Phenols with Aryl Iodides
    O. Bistri, A. Correa, C. Bolm, Angew. Chem. 2008, 120, 596–598; Angew. Chem. Int. Ed. 2008, 47, 586–588.

  • Copper-mediated Cross-Coupling Reactions of N-Protected Sulfonimidamides and Aryl Halides
    C. Worch, C. Bolm, Synthesis 2008, 739–742.

  • Iron-Catalyzed C-N Cross-Coupling of Sulfoximines with Aryl Iodides
    A. Correa, C. Bolm, Adv. Synth. Catal. 2008, 350, 391–394.

  • Iron-Catalyzed S-Arylation of Thiols with Aryl Iodides
    A. Correa, M. Carril, C. Bolm, Angew. Chem. 2008, 120, 2922–2925; Angew. Chem. Int. Ed. 2008, 47, 2880–2883.

  • Iron-Catalyzed N-arylations of amides
    A. Correa, S. Elmore, C. Bolm, Chem. Eur. J. 2008, 14, 3527–3529.

  • Iron-Catalyzed Sonogashira Reactions
    M. Carril, A. Correa, C. Bolm, Angew. Chem. 2008, 120, 4940–4943; Angew. Chem. Int. Ed. 2008, 47, 4862–4865.

  • Iron-Catalyzed Intramolecular O-Arylations: Synthesis of 2-Aryl Benzoxazoles
    J. Bonnamour, C. Bolm, Org. Lett. 2008, 10, 2665–2667.

  • Synthesis of diarylamines catalyzed by iron salts
    A. Correa, M. Carril, C. Bolm, Chem. Eur. J. 2008, 14, 10919–10922.

  • Ligand-Free Copper-Catalyzed N-Arylations of Nitrogen Nucleophiles
    A. Correa, C. Bolm, Adv. Synth. Catal. 2007, 349, 2673–2676.

  • Iron-Catalyzed N-Arylations of Nitrogen Nucleophiles
    A. Correa, C. Bolm, Angew. Chem. 2007, 119, 9018–9021; Angew. Chem. Int. Ed. 2007, 46, 8862–8865. Highlighted in C&EN, 2007, 85, 52.