Cyclic Sulfoximines as Methyl and Perdeuteromethyl Transfer Agents and Their Applications in Photoredox Catalysis
P. Wu, G. Goujon, S. Pan, B. Tuccio, B. Pégot, G. Dagousset, E. Anselmi, E. Magnier, C. Bolm, Angew. Chem. Int. Ed. 2024, 63, e202412418.
Sulfur-Based Building Blocks in BN- and BO-Doped Inorganic–Organic Hybrid Polymers
M. Maier, F. Brosge, J. S. Schneider, J. Bachmann, S. Schmidt, C. Bolm, H. Helten, Macromolecules 2024, 57, 6370–6378.
Syntheses of Sulfilimines by Iron-Catalyzed Iminations of Sulfides with 2,2,2-Trichloroethyl Sulfamate
K. Periasamy, S. Gordeeva, C. Bolm, J. Org. Chem. 2024, 89, 9705–9709.
Synthesis of Benzo[e][1,4,3]oxathiazin-3-one 1-Oxides from NH-S-(2-Hydroxyaryl)sulfoximines
K. Periasamy, P. van Bonn, R. Tschekorsky Orloff, N. Völcker, Q. Lu, K. Rissanen, C. Bolm, J. Org. Chem. 2024, 89, 8286–8290.
Azasulfur(IV) derivatives of sulfite and sulfinate esters by formal S–S bond insertion of dichloramines
P. Wu, J. Demaerel, B. J. Statham, C. Bolm, Chem. Sci. 2024, 15, 5333–5339.
Palladium-Catalyzed Domino Reaction for the Synthesis of 3-Amino 1,2,4-Benzothiadiazine 1,1-Dioxides
R. Hommelsheim, R. van Nahl, L. M. Hanek, J. S. Ward, K. Rissanen, C. Bolm, Adv. Synth. Catal. 2024, 366, 717–724.
A Copper-Catalyzed Interrupted Domino Reaction for the Synthesis of Fused Triazolyl Benzothiadiazine-1-oxides
R. Hommelsheim, S. Bausch, A. Selvakumar, M. M. Amer, K.-N. Truong, K. Rissanen, C. Bolm, Chem. Eur. J. 2023, 29, e202203729.
Synthesis of 3-amino-substituted benzothiadiazine oxides by a palladium-catalysed cascade reaction
R. Hommelsheim, S. Bausch, R. van Nahl, J. S Ward, K. Rissanen, C. Bolm, Green Chem. 2023, 25, 3021–3026.
Copper-Catalyzed N-Alkylations of NH-Sulfoximines Under Visible Light
P. Shi, Y. Tu, D. Ma, C. Bolm, Adv. Synth. Catal. 2023, 365, 1613–1617.
Synthesis of N-Monosubstituted Sulfondiimines by Metal-free Iminations of Sulfiliminium Salts
M. T. Passia, N. Bormann, Jas S. Ward, K. Rissanen, C. Bolm, Angew. Chem. Int. Ed. 2023, 62, e202305703.
Synthesis of Sulfonyl, Sulfonimidoyl, and Sulfoxyl Fluorides under Solvent-Free Mechanochemical Conditions in a Mixer Mill by Imidazole-to-Fluorine Exchange
M. T. Passia, M. M. Amer, J. Demaerel, C. Bolm, ACS Sustainable Chem. Eng. 2023, 11, 6838–6843.
Cyclic Sulfoximine and Sulfonimidamide Derivatives by Copper-Catalyzed Cross-Coupling Reactions with Elemental Sulfur
P. Wu, J. Ward, K. Rissanen, C. Bolm, Adv. Synth. Catal. 2023, 365, 522–526.
A One-Pot Domino Reaction Providing Fluorinated 5,6-Dihydro-1,2-thiazine 1-Oxides from Sulfoximines and 1-Trifluoromethylstyrenes
X. Wang, K. Rissanen, C. Bolm, Org. Lett. 2023, 25, 1569–1572
Synthesis of o-Sulfinylanilines from N-Alkyl Sulfoximines and Arynes
X. Wang, M. Frings, K. Rissanen, C. Bolm, J. Org. Chem. 2023, 88, 2666–2669.
Matching Carbenes and Sulfoximines via Ketenes Generated from α-Diazoketones by Blue Light
S. Pan, M. T. Passia, X. Wang, P. Wu, D. Ma, C. Bolm, Adv. Synth. Catal. 2023, 365, 31–36.
Electro-mechanochemical approach towards chloro sulfoximidations of allenes under solvent-free conditions in a ball mill
M. M. Amer, R. Hommelsheim, C. Schumacher, D. Kong, C. Bolm, Faraday Discuss. 2023, 241, 79–90.
Acid-Mediated Imidazole-to-Fluorine Exchange for the Synthesis of Sulfonyl and Sulfonimidoyl Fluorides
M. T. Passia, J. Demaerel, M. M. Amer, A. Drichel, S. Zimmer, C. Bolm, Org. Lett. 2022, 24, 8802–8805.
Evaluation of Chiral Organosulfur Compounds on Their Activity against the Malaria Parasite Plasmodium falciparum
C. J. Ngwa, R. Stratmann, J. P. Musabyimana, K. Pannen, J.-H. Schöbel, M. Frings, I. Schiffers, C. Quaranta, S. Koschmieder, N. Chatain, G. Pradel, C. Bolm, Trop. Med. Infect. Dis. 2022, 7, 416.
Superbase-Mediated gem-Difluoroalkenylations of Sulfoximines
X. Wang, C. Wang, C. Bolm, Org. Lett. 2022, 24, 7461–7464.
Copper-Catalyzed, Aerobic Synthesis of NH-Sulfonimidamides from Primary Sulfinamides and Secondary Amines
P. Wu, J. Demaerel, D. Kong, D. Ma, C. Bolm, Org. Lett. 2022, 24, 6988–6992.
The Preparation of Diaryl Sulfoxinium Triflates and Their Application in Palladium-Catalyzed Cross-Coupling Reactions
C. Wang, X. Wang, D. Kong, K.-N. Truong, K. Rissanen, C. Bolm, Chem. Asian J. 2022, 17, e202200828.
TACN-Mn Catalyst use in an Advanced Oxidation Process for Efficient Micropollutant Abatement in Wastewater: A Transformation Study of Diclofenac and Sulfamethoxazole
J. Wolters, M. Usman, J. Mathiä, D. Dirichs, D. Bastian, B. Aumeier, C. Bolm, V. Linnemann, T. Wintgens, J. Environ. Chem. Eng. 2022, 10, 108320.
Sulfonimidamides by Sequential Mechanochemical Chlorinations and Aminations of Sulfinamides
S. Terhorst, T. Jansen, T. Langletz, C. Bolm, Org. Lett. 2022, 24, 4109–4113.
2-Formyl Benzamides from an N-Phthalimidoyl Sulfoximine
Y. Tu, P. Shi, C. Bolm, Adv. Synth. Catal. 2022, 364, 1522–1525.
Stainless steel-initiated chloro sulfoximidations of allenes under solvent-free conditions in a ball mill
D. Kong, M. M. Amer, C. Bolm, Green Chem. 2022, 24, 3125–3129.
Factors Governing the Catalytic Insertion of CO2 into Arenes – A DFT Case Study for Pd and Pt Phosphane Sulfonamido Complexes
M. Hölscher, G. Kemper, S. Jenthra, C. Bolm, W. Leitner, Chem. Eur. J. 2022, 28, e202104375.
Visible-Light-Mediated α-Ketoacylations of NH-Sulfoximines with gem-Difluoroalkenes
Y. Tu, P. Shi, C. Bolm, Org. Lett. 2022, 24, 907–911.
Visible Light-Promoted Synthesis of β-Keto Sulfoximines from N-Tosyl-Protected Sulfoximidoyl Chlorides
P. Shi, Y. Tu, C. Wang, D. Ma, C. Bolm, J. Org. Chem. 2022, 87, 3817–3824.
Introduction of Lipophilic Side Chains to NH-Sulfoximines by Palladium Catalysis Under Blue Light Irradiation
D. Ma, D. Kong, P. Wu, Y. Tu, P. Shi, X. Wang, C. Bolm, Org. Lett. 2022, 24, 2238–2241.
Photochemistry of N-Phenyl Dibenzothiophene Sulfoximine
A. Isor, R. Hommelsheim, G. W. Cone, M. Frings, J. T. Petroff II, C. Bolm, R. D. McCulla, Photochem. Photobiol. 2021, 97, 1322–1334.
Highlighted by M. Rashid, D. D. Baker and A. Greer in Photochem. Photobiol. 2021, 97, 1453–1455.
Three-Dimensional Heterocycles by 5-exo-dig Cyclizations of S-Methyl-N-ynonylsulfoximines
D. Ma, D. Kong, C. Wang, K.-N. Truong, K. Rissanen, C. Bolm, Org. Lett. 2021, 23, 8287–8290.
Synthesis of trifluoromethyl-substituted 1,2,6-thiadiazine 1-oxides from sulfonimidamides under mechanochemical conditions
M. T. Passia, J.-H. Schöbel, N. J. Lentelink, K.-N. Truong, K. Rissanen, C. Bolm, Org. Biomol. Chem. 2021, 19, 9470–9475.
Palladium‐Catalyzed Carbonylation in the Synthesis of N‐Ynonylsulfoximines
D. Ma, C. Wang, D. Kong, Y. Tu, P. Shi, C. Bolm, Adv. Synth. Catal. 2021, 363, 1330–1334.
1,2-Benzothiazine Derivatives from Sulfonimidamides by Metal-Catalyzed Annulation Reactions in Solution and under Solvent-Free Mechanochemical Conditions
J.‐H. Schöbel, P. Elbers, K.‐N. Truong, K. Rissanen, C. Bolm, Adv. Synth. Catal. 2021, 363, 1322–1329.
2,3-Dihydro-1,2,6-thiadiazine 1-Oxides by Biginelli-Type Reactions with Sulfonimidamides under Mechanochemical Conditions
F. Krauskopf, K.‐N. Truong, K. Rissanen, C. Bolm, Org. Lett. 2021, 23, 2699–2703.
NH-sulfoximine: A novel pharmacological inhibitor of the mitochondrial F1Fo‐ATPase, which suppresses viability of cancerous cells
D. Strobbe, R. Pecorari, O. Conte, A. Minutolo, C. M. M. Hendriks, S. Wiezorek, D. Faccenda, R. Abeti, C. Montesano, C. Bolm, M. Campanella, Br. J. Pharmacol. 2021, 178, 298–311.
Sulfoximines with α‐Ketoester Functionalities at Nitrogen from Cyanoacetates and Air
C. Wang, H. Wang, C. Bolm, Adv. Synth. Catal. 2021, 363, 747–750.
Mechanochemical Synthesis of 1,2,6-Thiadiazine 1-Oxides from Sulfonimidamides and the Fluorescence Properties of the Products
J.-H. Schöbel, W. Liang, D. Wöll, C. Bolm, J. Org. Chem. 2020, 85, 15760–15766.
N-(2,3,5,6-Tetrafluoropyridyl)sulfoximines: synthesis, X-ray crystallography, and halogen bonding
C. Schumacher, H. Fergen, R. Puttreddy, K.-N. Truong, T. Rinesch, K. Rissanen, C. Bolm, Org. Chem. Front. 2020, 7, 3896–3906.
Use of Hypervalent Iodine Reagents in Visible Light-Promoted α-Ketoacylations of Sulfoximines with Aryl Alkynes
C. Wang, D. Ma, Y. Tu, C. Bolm, Org. Lett. 2020, 22, 8937–8940.
Synthesis of Benzothiadiazine-1-oxides by Rhodium-Catalyzed C–H Amidation/Cyclization
P. Shi, Y. Tu, C. Wang, D. Kong, D. Ma, C. Bolm, Org. Lett. 2020, 22, 8842–8845.
The Sulfilimine Analogue of Allicin, S-Allyl-S-(S-allyl)-N-Cyanosulfilimine, Is Antimicrobial and Reacts with Glutathione
T. Horn, W. Bettray, U. Noll, F. Krauskopf, M.-R. Huang, C. Bolm, A. J. Slusarenko, M. C. H. Gruhlke, Antioxidants 2020, 9, 1086.
Chiral Analogues of PFI-1 as BET Inhibitors and Their Functional Role in Myeloid Malignancies
B. Altenburg, M. Frings, J.-H. Schöbel, J. Goßen, K. Pannen, K. Vanderliek, G. Rossetti, S. Koschmieder, N. Chatain, C. Bolm, ACS Med. Chem. Lett. 2020, 11, 1928–1934. Part of the special issue “Medicinal Chemistry: From Targets to Therapies”.
Photocatalytic Fluoro Sulfoximidations of Styrenes
C. Wang, Y. Tu, D. Ma, C. Bolm, Angew. Chem. 2020, 132, 14238–14241; Angew. Chem. Int. Ed. 2020, 59, 14134–14137.
5-Carbonyl-1,3-oxazine-2,4-diones from N-Cyanosulfoximines and Meldrum’s Acid Derivatives
F. Brosge, J. F. Kochs, M. Bregu, K.-N. Truong, K. Rissanen, C. Bolm, Org. Lett. 2020, 22, 6667–6670.
1,2,6-Thiadiazine 1-Oxides: Unsaturated Three-Dimensional S,N-Heterocycles from Sulfonimidamides
J.-H. Schöbel, M. T. Passia, N. A. Wolter, R. Puttreddy, K. Rissanen, C. Bolm, Org. Lett. 2020, 22, 2702–2706.
[3+2]‐Cycloadditions of N‐Cyano Sulfoximines with 1,3‐Dipoles
F. Krauskopf, K.‐N. Truong, K. Rissanen, C. Bolm, Eur. J. Org. Chem. 2020, 2761–2765.
Novel Broccoli Sulforaphane-Based Analogues Inhibit the Progression of Pancreatic Cancer without Side Effects
C. Georgikou, L. Buglioni, M. Bremerich, N. Roubicek, L. Yin, W. Gross, C. Sticht, C. Bolm, I. Herr, Biomolecules 2020, 10, 769.
BN‐ and BO‐Doped Inorganic–Organic Hybrid Polymers with Sulfoximine Core Units
F. Brosge, T. Lorenz, H. Helten, C. Bolm, Chem. Eur. J. 2019, 25, 12708–12711. Selected as Hot Paper.
Conversion and degradation pathways of sulfoximines
S. Wiezorek, P. Lamers, C. Bolm, Chem. Soc. Rev. 2019, 48, 5408–5423.
Additions to N‐Sulfinylamines as an Approach for the Metal‐free Synthesis of Sulfonimidamides: O‐Benzotriazolyl Sulfonimidates as Activated Intermediates
M. Bremerich, C. M. Conrads, T. Langletz, C. Bolm, Angew. Chem. 2019, 131, 19190–19196; Angew. Chem. Int. Ed. 2019, 58, 19014–19020. Selected as Hot Paper.
Inhibitoren für Bromodomänen
M. Frings, J.-H. Schoebel, B. Altenburg, N. Chatain, S. Koschmieder, G. Rossetti, J. Gossen, C. Bolm, Patentanmeldung, Anmeldenummer DE 10 2019 129 527.0, October 31, 2019.
Organocatalytic Synthesis of Sulfoximidoyl-Containing Carbamates from Sulfoximines and Morita–Baylis–Hillman Carbonates
Z. Li, M. Frings, H. Yu, C. Bolm, Org. Lett. 2019, 21, 3119–3122.
From One-Pot NH-Sulfoximidations of Thiophene Derivatives to Dithienylethene-Type Photoswitches
B. Verbelen, E. Siemes, A. Ehnbom, C. Räuber, K. Rissanen, D. Wöll, C. Bolm, Org. Lett. 2019, 21, 4293–4297.
Regioselective Syntheses of 1,2‐Benzothiazine 1‐Imines by Rhodium‐Catalyzed Annulation Reactions of Sulfondiimines
R. A. Bohmann, J.-H. Schöbel, Y. Unoh, M. Miura, C. Bolm, Adv. Synth. Catal. 2019, 361, 2000–2003. Selected as Very Important Publication.
3D Heterocycles from Sulfonimidamides by Sequential C–H Bond Alkenylation/Aza‐Michael Cyclization
A.-K. Bachon, A. Hermann, C. Bolm, Chem. Eur. J. 2019, 25, 5889–5892. Selected as Hot Paper.
Electrophilic Sulfoximidations of Thiols by Hypervalent Iodine Reagents
H. Wang, D. Zhang, M. Cao, C. Bolm, Synthesis 2019, 51, 271–275.
Photocatalytic Additions of 1-Sulfoximidoyl-1,2-Benziodoxoles to Styrenes
H. Wang, D. Zhang, C. Bolm, Chem. Eur. J. 2018, 24, 14942–14945.
Copper‐Catalyzed Transsulfinamidation of Sulfinamides as a Key Step in the Preparation of Sulfonamides and Sulfonimidamides
H. Yu, Z. Li, C. Bolm, Angew. Chem. 2018, 130, 15828–15831; Angew. Chem. Int. Ed. 2018, 57, 15602–15605.
Transition-Metal-Free Arylations of In-Situ Generated Sulfenates with Diaryliodonium Salts
H. Yu, Z. Li, C. Bolm, Org. Lett. 2018, 20, 7104–7106.
Organocatalytic Asymmetric Allylic Alkylations of Sulfoximines
Z. Li, M. Frings, H. Yu, G. Raabe, C. Bolm, Org. Lett. 2018, 20, 7367–7370.
Three‐Dimensional Heterocycles by Iron‐Catalyzed Ring‐Closing Sulfoxide Imidation
H. Yu, Z. Li, C. Bolm, Angew. Chem. 2018, 130, 12229–12232; Angew. Chem. Int. Ed. 2018, 57, 12053–12056.
Photocatalytic difunctionalisations of alkenes with N-SCN sulfoximines
D. Zhang, H. Wang, C. Bolm, Chem. Commun. 2018, 54, 5772–5775.
Nondirected Copper-Catalyzed Sulfoxidations of Benzylic C–H Bonds
H. Yu, Z. Li, C. Bolm, Org. Lett. 2018, 20, 2076–2079.
Sulforaphane Modifies Histone H3, Unpacks Chromatin, and Primes Defense
B. Schillheim, I. Jansen, S. Baum, A. Beesley, C. Bolm, U. Conrath, Plant Physiol. 2018, 176, 2395–2405.
N-Arylated Sulfoximines as Cross-Coupling Building Blocks
A.-K. Bachon, A.-D. Steinkamp, C. Bolm, Adv. Synth. Catal. 2018, 360, 1088–1093.
Sulfoximidations of Benzylic C–H Bonds by Photocatalysis
H. Wang, D. Zhang, C. Bolm, Angew. Chem. 2018, 130, 5965–5968; Angew. Chem. Int. Ed. 2018, 57, 5863–5866.
Tetrahydrobenzo[c]thieno[2,1-e]isothiazole 4-Oxides: Three-Dimensional Heterocycles as Cross-Coupling Building Blocks
P. Lamers, C. Bolm, Org. Lett. 2018, 20, 116–118.
Iron(II)-Catalyzed Direct Synthesis of NH Sulfoximines from Sulfoxides
H. Yu, Z. Li, C. Bolm, Angew. Chem. 2018, 130, 330–333; Angew. Chem. Int. Ed. 2018, 57, 324–327.
Sulfoximidoyl-Containing Hypervalent Iodine(III) Reagents: 1-Sulfoximidoyl-1,2-benziodoxoles
H. Wang, D. Zhang, H. Sheng, C. Bolm, J. Org. Chem. 2017, 82, 11854–11858.
Rhodium-Catalyzed [4+3] Annulations of Sulfoximines with α,β-Unsaturated Ketones Leading to 1,2-Benzothiazepine 1-Oxides
J. Wen, H. Cheng, G. Raabe, C. Bolm, Org. Lett. 2017, 19, 6020–6023.
Copper-Catalyzed C(sp2)–S Coupling Reactions for the Synthesis of Aryl Dithiocarbamates with Thiuram Disulfide Reagents
Z.-B. Dong, X. Liu, C. Bolm, Org. Lett. 2017, 19, 5916–5919.
An Iodine-Mediated Hofmann-Löffler-Freytag Reaction of Sulfoximines Leading to Dihydroisothiazole Oxides
D. Zhang, H. Wang, C. Cheng, J. G. Hernández, C. Bolm, Adv. Synth. Catal. 2017, 359, 4274–4277.
Sulfoximidoyl-Containing Hypervalent Iodine(III) Reagents: 1-Sulfoximidoyl-1,2-benziodoxoles
H. Wang, D. Zhang, H. Sheng, C. Bolm, J. Org. Chem. 2017, 82, 11854 – 11858.
Synthesis of N-Propargylsulfoximines by Copper-Catalyzed A3-Couplings
H. Cheng, J. Wen, C. Bolm, Chem. Eur. J. 2017, 23, 12100–12103.
Dibenzothiophene Sulfoximine as NH3 Surrogate in the Synthesis of Primary Amines by Copper-Catalyzed C–X and C–H Bond Amination
Z. Li, H. Yu, C. Bolm, Angew. Chem. 2017, 129, 9660–9663; Angew. Chem. Int. Ed. 2017, 56, 9532–9535.
Sulfoximines as ATR inhibitors: Analogs of VE-821
C. M. M. Hendriks, J. Hartkamp, S. Wiezorek, A.-D. Steinkamp, G. Rossetti, B. Lüscher, C. Bolm, Bioorg. Med. Chem. Lett. 2017, 27, 2659–2662.
1,2-Benzothiazines from Sulfoximines and Allyl Methyl Carbonate by Rhodium-Catalyzed Cross-Coupling and Oxidative Cyclization
J. Wen, D. P. Tiwari, C. Bolm, Org. Lett. 2017, 19, 1706–1709.
Rhodium(III)-Catalyzed Ortho Halogenations of N-Acylsulfoximines and Synthetic Applications toward Functionalized Sulfoximine Derivatives
Y. Cheng, W. Dong, K. Parthasarathy, C. Bolm, Org. Lett. 2017, 19, 726–729.
Access to N-Cyanosulfoximines by Transition Metal-Free Iminations of Sulfoxides
C. A. Dannenberg, L. Fritze, F. Krauskopf, C. Bolm, Org. Biomol. Chem. 2017, 15, 1086–1090
Sulfoximines from a Medicinal Chemist’s Perspective: Physicochemical and in vitro Parameters Relevant for Drug Discovery
M. Frings, C. Bolm, A. Blum, C. Gnamm, Eur. J. Med. Chem. 2017, 126, 225–245.
Synthesis of a sulfonimidamide-based analog of Tasisulam and its biological evaluation in the melanoma cell lines SKMel23 and A375
A.-D. Steinkamp, L. Schmitt, X. Chen, K. Fietkau, R. Heise, J. Baron, C. Bolm, Skin Pharmacol. Physiol. 2016, 29, 281–290.
Benzo[c]isothiazole-2-oxides: Three-Dimensional Heterocycles with Cross-Coupling und Functionalization Potential
P. Lamers, L. Buglioni, S. Koschmieder, N. Chatain, C. Bolm, Adv. Synth. Catal. 2016, 358, 3649–3653.
A Building Block Approach for the Synthesis of Sulfoximines
A.-D. Steinkamp, S. Wiezorek, F. Brosge, C. Bolm, Org. Lett. 2016, 18, 5348–5351.
Selected by P. Knochel and J. M. Hammann for Synfacts 2016, 12, 1287.
Synthesis of Sulfoximidoyl-Containing Hypervalent Iodine(III) Reagents and Their Use in Transition-Metal-Free Sulfoximidations of Alkynes
H. Wang, Y. Cheng, P. Becker, G. Raabe, C. Bolm, Angew. Chem. 2016, 128, 12845–12848; Angew. Chem. Int. Ed. 2016, 55, 12655–12658.
Selected by T. M. Swager and P. Wang for Synfacts 2016, 12, 1030.
Exploring the Reactivity of N-Alkynylated Sulfoximines: Acid-Catalyzed Cyclizations
R. Pirwerdjan, P. Becker, C. Bolm, Org. Lett. 2016, 18, 3307–3309.
Lithium Sulfondiimidoyl Carbanions
R. A. Bohmann, J.-H. Schöbel, C. Bolm, Synlett 2016, 27, 2201–2204.
Rhodium-Catalyzed ortho-Amidations in the Preparation of Thiadiazine 1-Oxides
Y. Cheng, W. Dong, H. Wang, C. Bolm, Chem. Eur. J. 2016, 22, 10821–10824.
Halocyclizations of Unsaturated Sulfoximines
H. Wang, M. Frings, C. Bolm, Org. Lett. 2016, 18, 2431–2434.
1,2-Thiazines: One-Pot Syntheses Utilizing Mono- and Diaza-Analogs of Sulfones
R. A. Bohmann, Y. Unoh, M. Miura, C. Bolm, Chem. Eur. J. 2016, 22, 6783–6786.
Copper-Catalyzed S–C/S–N Bond Interconversions
J. Wen, H. Cheng, S. Dong, C. Bolm, Chem. Eur. J. 2016, 22, 5547–5550.
Organocatalytic Kinetic Resolution of Sulfoximines
S. Dong, M. Frings, H. Cheng, J. Wen, D. Zhang, G. Raabe, C. Bolm, J. Am. Chem. Soc. 2016, 138, 2166–2169.
Selected by B. List and L. Liu for Synfacts 2016, 12, 634.
Copper-Catalyzed Oxidative α-Ketoacylations of Sulfoximines with Aryl Methyl Ketones and Dioxygen as Terminal Oxidant
H. Cheng, C. Bolm, Synlett 2016, 27, 769–772.
Copper-Catalyzed Direct Sulfoximination of Heteroaromatic N-Oxides by Dual C–H/N–H Dehydrogenative Cross-Coupling
H. Yu, Z. Li, C. A. Dannenberg, C. Bolm, Chem. Asian J. 2016, 11, 54–57.
Exploring the Reactivity of N-Alkynylated Sulfoximines: Regioselective Hydroacyloxylations and Hydroaminations
R. Pirwerdjan, P. Becker, C. Bolm, Org. Lett. 2015, 17, 5008–5011.
Synthesis of N-Cyano-substituted Sulfilimine and Sulfoximine Derivatives of S0859 and their Biological Evaluation as Sodium Bicarbonate Co-transport Inhibitors
A.-D. Steinkamp, N. Seling, S. Lee, E. Boedtkjer, C. Bolm, MedChemCommun 2015, 6, 2163–2169.
Pentafluorosulfanyl-containing flufenamic acid analogs: Syntheses, properties and biological activities
C. M. M. Hendriks, T. M. Penning, T. Zang, D. Wiemuth, S. Gründer, I. A. Sanhueza, F. Schoenebeck, C. Bolm, Bioorg. Med. Chem. Lett. 2015, 25, 4437–4440.
The Iron-Catalyzed Acylative Dealkylation of N-Alkyl Sulfoximines
P. Lamers, D. L. Piebbenow, C. Bolm, Eur. J. Org. Chem 2015, 5594–5602.
N-Trifluoromethylthiolated Sulfoximines
C. Bohnen, C. Bolm, Org. Lett. 2015, 17, 3011–3013.
Rhodium-Catalyzed Direct Coupling of Benzothioamides with Alkenes and Alkynes through Directed C-H Bond Cleavage
Y. Yokoyama, Y. Unoh, R. A. Bohmann, T. Satoh, K. Hirano, C. Bolm, M. Miura, Chem. Lett. 2015, 44, 1104–1106. (Editor's Choice)
Silver-Mediated N-Trifluoromethylations of Sulfoximines
F. Teng, J. Cheng, C. Bolm, Org. Lett. 2015, 17, 3166–3169.
The Synthesis of Chiral Benzothiazine and Thiazinoquinoline Derivatives
L. Wang, D. L. Priebbenow, X. Y. Chen, F.-F. Pan, C. Bolm, Eur. J. Org. Chem. 2015, 3338–3343.
Regioselective Syntheses of 1,2-Benzothiazines by Rhodium-Catalyzed Annulation Reactions
Y. Cheng, C. Bolm, Angew. Chem. 2015, 127, 12526–12529, Angew. Chem. Int. Ed. 2015, 54, 12349–12352.
Selected by V. Snieckus and M. A. J. Miah for Synfacts 2015, 11, 691.
Direct access to N-alkyl sulfoximines from sulfides by a sequential imidation/oxidation procedure
C. A. Dannenberg, V. Bizet, C. Bolm, Synthesis 2015, 47, 1951–1959.
Zolimidine Analogs: The Synthesis of Imidazo[1,2-a]pyridine-based Sulfilimines and Sulfoximines
C. M. M. Hendriks, P. Nürnberg, C. Bolm, Synthesis 2015, 47, 1190–1194.
Sulfur Imidations by Light-Induced Ruthenium-Catalyzed Nitrene Transfer Reactions
V. Bizet, C. Bolm, Eur. J. Org. Chem. 2015, 2854–2860.
Methyl 4-Pentafluorosulfanylphenyl Sulfoximines
C. M. M. Hendriks, J. Reball, C. Bolm, Synlett 2015, 26, 73–75.
(R)-(−)-2-[(5-Oxido-5-phenyl-5λ4-isoquino[4,3-c][2,1]benzothiazin-12-yl)amino]benzonitrile
M. Frings, I. Atodiresei, C. Bolm, Molbank 2014, M834.
Hydroarylations of Heterobicyclic Alkenes through Rhodium-Catalyzed Directed C-H Functionalizations of S-Aryl Sulfoximines
W. Dong, K. Parthasarathy, Y. Cheng, F. Pan, C. Bolm, Chem. Eur. J. 2014, 20, 15732–15726.
Copper-Catalyzed N-Alkynylations of Sulfoximines with Bromoacetylenes
X. Y. Chen, L. Wang, M. Frings, C. Bolm, Org. Lett. 2014, 16, 3796–3799.
Fluorinated Sulfoximines: Syntheses, Properties and Applications
V. Bizet, R. Kowalczyk, C. Bolm, Chem. Soc. Rev. 2014, 43, 2426–2438.
Methionine and Buthionine Sulfoximine: Syntheses under Mild and Safe Imidation/Oxidation Conditions
L. Buglioni, V. Bizet, C. Bolm, Adv. Synth. Catal. 2014, 356, 2209–2213.
N-Arylations of Sulfoximines with 2-Arylpyridines by Copper-Mediated Dual N-H/C-H Activation
L. Wang, D. L. Priebbenow, W. Dong, C. Bolm, Org. Lett. 2014, 16, 2661–2663.
Iron-Catalyzed Hetero Cross-Dehydrogenative Coupling Reactions of Sulfoximines with Diarylmethanes: A New Route to N-Alkylated Sulfoximines
Y. Cheng, W. Dong, L. Wang, K. Parthasarathy, C. Bolm, Org. Lett. 2014, 16, 2000–2002.
N-Alkylations of NH-Sulfoximines and NH-Sulfondiimines with Alkyl Halides Mediated by KOH in DMSO
C. M. M. Hendriks, R. A. Bohmann, M. Bohlem, C. Bolm, Adv. Synth. Catal. 2014, 356, 1847–1852.
C–H Activation of Methyl Arenes in the MnO2-Mediated Aroylation of N-Chlorosulfoximines
D. L. Priebbenow, C. Bolm, Org. Lett. 2014, 16, 1650–1652.
Selected by P. Knochel and N. M. Barl for Synfacts 2014, 10, 627.
Light-Induced Ruthenium-Catalyzed Nitrene Transfer Reactions: A Photochemical Approach towards N-Acyl Sulfimides and Sulfoximines
V. Bizet, L. Buglioni, C. Bolm, Angew. Chem. 2014, 126, 5745–5748; Angew. Chem. Int. Ed. 2014, 53, 5639–5642.
Rhodium(III)-Catalyzed Selective ortho-Olefinations of N-Acyl and N-Aroyl Sulfoximines by C-H Bond Activation
K. Parthasarathy, C. Bolm, Chem. Eur. J. 2014, 16, 4896–4900.
Catalytic, Asymmetric Synthesis of Phosphonic γ-(Hydroxyalkyl)butenolides with Contiguous Quaternary and Tertiary Stereogenic Centers
M. Frings, I. Thomé, I. Schiffers, F.-F. Pan, C. Bolm, Chem. Eur. J. 2014, 20, 1691–1700.
Iron-Catalyzed Imidative Kinetic Resolutions of Racemic Sulfoxides
J. Wang, M. Frings, C. Bolm, Chem. Eur. J. 2014, 20, 966–969.
Copper-Catalyzed Oxidative Decarboxylative Couplings of Sulfoximines and Aryl Propiolic Acids
D. L. Priebbenow, P. Becker, C. Bolm, Org. Lett. 2013, 15, 6155–6157.
Exploring the Reactivity of N-Alkynylated Sulfximines: [2+2]-Cyloadditions
R. Pirwerdjan, D. L. Priebbenow, P. Becker, P. Lamers, C. Bolm, Org. Lett. 2013, 15, 5397–5399.
Sulfoxides-to-Sulfimine Conversions: Use of Modified Burgess-type Reagents
C. M. M. Hendriks, P. Lamers, J. Engel, C. Bolm, Adv. Synth. Catal. 2013, 355, 3363–3368.
Rhodium-Catalyzed C3-Selective Alkenylation of Substituted Thiophene-2-Carboxylic Acids and Related Compounds
T. Litsuka, P. Schaal, K. Hirano, T. Satoh, C. Bolm, M. Miura, J. Org. Chem. 2013, 78, 7216–7222.
Copper-Catalyzed C-N Cross-Coupling of Sulfondiimines with Boronic Acids
R. Bohmann, C. Bolm, Org. Lett. 2013, 15, 4277–4279.
Copper-Catalyzed Synthesis of α-Thioaryl Carbonyl Compounds Through S–S and C–C Bonds Cleavage
L-H. Zou, D. L. Priebbenow, L. Wang, J. Mottweiler, C. Bolm, Adv. Synth. Catal. 2013, 355, 2558–2563.
Enantioselective Nitrene Transfer to Sulfides Catalyzed by a Chiral Iron Complex
J. Wang, M. Frings, C. Bolm, Angew. Chem. 2013, 125, 8823–8827; Angew. Chem. Int. Ed. 2013, 52, 8661–8665.
Selected by H. Hayashi and Y. Shimoda for Synfacts 2013, 9, 1188.
The copper-catalysed oxidative N-acylation of sulfoximines
L. Wang, D. L. Priebbenow, L.-H. Zou, C. Bolm, Adv. Synth. Catal. 2013, 355, 1490–1494.
Copper-Catalyzed Oxidative Cross-Couplings of Sulfoximines and Alkynes
L. Wang, H. Huang, D. L. Priebbenow, F.-F. Pan, C. Bolm, Angew. Chem. 2013, 125, 3562–3564; Angew. Chem. Int. Ed. 2013, 52, 3478–3480.
Selected by P. Knochel and N. M. Barl for Synfacts 2013, 9, 651.
N-Cyano Sulfoximines: COX Inhibition, anti-Cancer Activity, Cellular Toxicity, and Mutagenicity
S. J. Park, H. Baars, H. Buschmann, J. M. Baron, P. M. Amann, K. Czaja, H. Hollert, K. Bluhm, R. Redelstein, C. Bolm, ChemMedChem. 2013, 8, 217–220.
SIAPhos: Phosphorylated Sulfonimidamides and their Use in Iridium-Catalyzed Asymmetric Hydrogenations of Sterically Hindered Cyclic Enamides
F. W. Patureau, C. Worch, M. A. Siegler, A. L. Spek, C. Bolm, J. N. H. Reek, Adv. Synth. Catal. 2012, 354, 59–64.
Sulfoximines: Ligands for Asymmetric Metal Catalysis, Syntheses, and Bioactivities
C. Bolm, Latv. J. Chem. 2012, 49–50.
Synthesis of Sulfondiimines by NCS-Mediated Oxidative Imination of Sulfiliminium Salts
M. Candy, C. Guyon, S. Mersmann, J.-R. Chen, C. Bolm, Angew. Chem. 2012, 124, 4516–4519; Angew. Chem. Int. Ed. 2012, 51, 4440–4443.
Syntheses and biological activities of sulfoximine-based acyclic triaryl olefins
X. Y. Chen, S. J. Park, H. Buschmann, M. De Rosa, C. Bolm, Bioorg. Med. Chem. Lett. 2012, 22, 4307–4309.
Synthesis of N-Methyl-2-indolyl- and N-Methyl-2-benzo[b]furyl-Substituted Sulfoximines by Pd/Cu Co-catalyzed Domino Cross-Coupling/Cyclization Reactions
R. F. Schumacher, A. Honraedt, C. Bolm, Eur. J. Org. Chem. 2012, 3737–3741.
Synthesis of Chiral Sulfoximine-based Thioureas and their Application in Asymmetric Organocatalysis
M. Frings, I. Thomé, C. Bolm, Beilstein J. Org. Chem. 2012, 8, 1443–1451.
Palladium-Catalyzed C-N Cross-Coupling of N'-Monosubstituted Sulfondiimines with Aryl Bromides
M. Candy, R. Bohmann, C. Bolm, Adv. Synth. Catal. 2012, 354, 2928–2932.
Sulfoximine- and Sulfilimine-based DAPSON Analoga: Syntheses and Bioactivities
X. Chen, H. Buschmann, C. Bolm, Synlett 2012, 23, 2808–2810.
Copper-Catalyzed Direct Sulfoximination of Azoles and Polyfluoroarenes under Ambient Conditions
M. Miyasaka, K. Hirano, T. Satoh, R. Kowalczyk, C. Bolm, M. Miura Org. Lett. 2011, 13, 359–361.
Selected by P. Knochel and T. Kunz for Synfacts 2011, 4, 421.
Synthesis of CF3-Substituted Sulfoximines from Sulfoimidoyl Fluorides
R. Kowalczyk, A. J. F. Edmunds, R. G. Hall, C. Bolm, Org. Lett. 2011, 13, 768–771.
Synthesis of phosphorylated sulfoximines and sulfinamides and their application as ligands in asymmetric metal catalysis
E. B. Benetskiy, C. Bolm, Tetrahedron: Asymmetry 2011, 22, 373–378.
Bioactive Sulfoximines: Syntheses and properties of Vioxx® analogs
S. J. Park, H. Buschmann, C. Bolm, Bioorg. Med. Chem. Lett. 2011, 21, 4888–4890.
Asymmetric Synthesis of S,S-Dialkyl-Substituted Sulfoximines and Related Heterocycles
A. G. Pandey, M. J. McGrath, O. García Mancheño, C. Bolm, Synthesis 2011, 3827–3828.
Synthesis of Enantiopure Sulfonimidamides and Elucidation of Their Absolute Configuration by Comparison of Measured and Calculated CD Spectra and X-Ray Crystal Structure Determination
C. Worch, I. Atodiresei, G. Raabe, C. Bolm, Chem. Eur. J. 2010, 16, 677–683.
Synthesis of Sulfoximines and Sulfilimines with Aryl and Pyrazolylmethyl Substituents
O. García Mancheño, J. Dallimore, A. Plant, C. Bolm, Adv. Synth. Catal. 2010, 352, 309–316.
C1-Symmetric Aminosulfoximines in Copper-Catalyzed Asymmetric Vinylogous Mukaiyama Aldol Reactions
M. Frings, I. Atodiresei, Y. Wang, J. Runsink, G. Raabe, C. Bolm, Chem. Eur. J. 2010, 16, 4577–4587.
Synthesis of Amino-Functionalized Sulfonimidamides and Their Application in the Enantioselective Henry Reaction
M. Steurer, C. Bolm, J. Org. Chem. 2010, 75, 3301–3310.
Selected by M. Lautens and C. Tsui for Synfacts 2010, 8, 912.
Enantioselective Synthesis of Highly Functionalized Amides by Copper-Catalyzed Vinylogous Mukaiyama Aldol Reaction
M. Frings, D. Goedert, C. Bolm, Chem. Commun. 2010, 46, 5497–5499.
Metal-Free Synthesis of N-Cyano-Substituted Sulfilimines and Sulfoximines
A. Pandey, C. Bolm, Synthesis 2010, 2922–2925.
Light-Induced Synthesis of π-Extended Tetrathiafulvalenes Incorporating Ferrocenes. An Efficient Route for the Synthesis of Electron Donor Materials
A. A. O. Sarhan, C. Bolm, Synthesis 2009, 1000–1006.
Catalyzed Vinylogous Mukaiyama Aldol Reactions With Controlled Enantio- and Diastereoselectivities
M. Frings, I. Atodiresei, J. Runsink, G. Raabe, C. Bolm, Chem. Eur. J. 2009, 15, 1566–1569.
Selected by H. Yamamoto and J. N. Payette for Synfacts 2009, 5, 509.
Iron(II) Triflate as Efficient Catalyst for the Imination of Sulfoxides
O. García Mancheño, J. Dallimore, A. Plant, C. Bolm, Org. Lett. 2009, 11, 2429–2432.
Ring-Closing Enyne Metathesis (RCEYM) for the Synthesis of Cyclic Sulfoximines
B. Füger, C. Bolm, Synlett 2009, 1601–1604.
Enantioselective Halogenations of β-Ketoesters Catalyzed by a Chiral Copper Sulfoximine Complex
M. Frings, C. Bolm, Eur. J. Org. Chem. 2009, 121, 4085–4090.
Use of Prolyl Sulfonimidamides in Solvent-Free Organocatalytic Asymmetric Aldol Reactions
C. Worch, C. Bolm, Synlett 2009, 2425–2428.
Synthesis of Sulfoximidoyl-Substituted Triazoles by Huisgen 1,3-Dipolar Cycloaddition
B. Füger, G. Sklute, I. Marek, G. Y. Bolm, C. Bolm, Synlett 2008, 116–118.
Synthesis of Sulfoximine-Derived P,N-Ligands and Their Applications in Asymmetric Hydrogenation Reactions
S.-M. Lu, C. Bolm, Adv. Synth. Catal. 2008, 350, 1101–1105.
C1-Symmetric Oxazolinyl-Sulfoximines as Ligands in Copper-Catalyzed Asymmetric Mukaiyama Aldol Reactions
J. Sedelmeier, J. Hammerer, C. Bolm, Org. Lett. 2008, 10, 917–920.
Oxidation of Heteroatoms (N and S)
O. García Mancheño, C. Bolm, in Iron Catalysis in Organic Chemistry (Ed.: B. Plietker), Wiley-VCH, 2008, 109–123.
Synthesis and use of chiral sulfoximines
C. Worch, A. C. Mayer, C. Bolm, in Organosulfur Chemistry in Asymmetric Synthesis (Eds.: T. Toru, C. Bolm), Wiley-VCH, 2008, 209–229.
Editorship of Organosulfur Chemistry in Asymmetric Synthesis (Eds.: T. Toru, C. Bolm), Wiley-VCH, Weinheim, Germany 2008 (432 pages).
Efficient Synthesis of Sulfonimidoylguanidines by Coupling of Sulfonimidamides with Uronium Reagents
C. Worch, C. Bolm, Synthesis 2007, 1355–1358.
Sulfoximines as ligands in asymmetric metal catalysis (Personal Account)
C. Bolm, in Asymmetric Synthesis with Chemical and Biological Methods (Eds.: D. Enders, K.-E. Jaeger), Wiley/VCH, Weinheim 2007, 149–176.
Comparative Study of Metal-Catalyzed Iminations of Sulfoxides and Sulfides
O. García Mancheño, C. Bolm, Chem. Eur. J. 2007, 13, 6674–6681.
Synthesis of N-(1H)-Tetrazole Sulfoximines
O. García Mancheño, C. Bolm, Org. Lett. 2007, 9, 2951–2954.
Iodinane- and Metal-free Synthesis of N-Cyano Sulfilimines: Novel and Easy Access to NH-Sulfoximines
O. García Mancheño, O. Bistri, C. Bolm, Org. Lett. 2007, 9, 3809–3811.
Application of β-Hydroxysulfoximines in Catalytic Asymmetric Phenyl Transfer Reaction for the Synthesis of Diarylmethanols
J. Sedelmeier, C. Bolm, J. Org. Chem. 2007, 72, 8859–8862.
The use of chiral lithium amides in the desymmetrisation of N-trialkylsilyl dimethyl sulfoximines
M. J. McGrath, C. Bolm, Beilstein J. Org. Chem. 2007, 3, 33.
Synthesis of Sulfonimidamides from Sulfinamides by Oxidation with N-Chlorosuccinimide
O. García Mancheño, C. Bolm, Beilstein J. Org. Chem. 2007, 3, 25.